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You are viewing titles for THE UNIVERSITY OF NORTH CAROLINA AT CHAPEL HILL in the Organic chemistry available through the UMI Dissertations & Thesis Gradwoorks site
 
Development of anti-selective aldol additions and a convergent assembly of polycyclic ethers: Synthesis of the ABCDE fragment of brevetoxin A
 Molecular recognition in synthetic systems: I. Rigidified dendritic systems for imparting enantioselective molecular recognition to platinum-containing molecularly imprinted polymers, II. Using laser polarimetry to identify an enantioselective receptor for (-)-adenosine from a racemic dynamic combinatorial library
 
An improved synthesis of the AB spiroketal of spongistatin and synthetic studies toward yokonolide A
 Characterization of amino acid and peptide radicals and radical cations and their use as probes for the aqueous microenvironment
 
Enantioselective metallophosphite-catalyzed nucleophilic acylation of alpha,beta-unsaturated amides and nitrones
 The [1,2]-Brook rearrangement: Novel carbon-carbon bond forming reactions and application to the total synthesis of zaragozic acid C
 
Non-covalent interactions in beta-hairpin peptides and small molecule model systems
 Lasonolide A: Synthetic explorations
 
Approaches to marine-derived polycyclic ether natural products: First total syntheses of the asbestinins and a convergent strategy for brevetoxin A
 Catalytic electrophilic amination reactions
 
A highly convergent approach to brevetoxin A
 Synthesis and characterization of dendrimer-based nitric oxide delivery systems
 
Benzoin-type reactions and tandem C-C bond forming reactions using acyl anion equivalents
 The total synthesis of alternaric acid and progress toward the synthesis of subglutinol
 
Progress towards the total synthesis of pyrancin
 Functional aliphatic polyesters based on cycloaddition methodologies
 
Recognition of nucleotides and peptides using designed beta-hairpin peptides and dynamic combinatorial chemistry
 Gold-catalyzed cyclization reactions of allenes
 
Development of dynamic substrates for studies of cell adhesion and migration
 I. Mechanistic studies of a copper-catalyzed electrophilic amination of diorganozinc reagents by O-benzoyl N,N-dialkylhydroxylamines II. Development of a 3-exo-dig cyclization for the preparation of vinylidene cyclopropanes III. Total synthesis of (+)-polyanthellin A
 
Efforts towards the total synthesis of (+)-sorangicin A
 Lewis acid-catalyzed cycloaddition reactions of donor-acceptor cyclopropanes
 
Highly selective auxiliary-mediated acetate aldol additions and progress towards the total synthesis of (-)-brevenal
 I. [1,2]-Brook rearrangement: Application of silyl glyoxylates in a novel glycolate aldol reaction and in a controlled oligomerization to complete the total synthesis of zaragozic acid C. II. Progress toward the total synthesis of pactamycin
 
Metal-catalyzed annulations of strained cycloalkanes
 The development of polycationic materials for gene delivery applications
 
Total synthesis of irciniastatin A
 Advances in the synthesis, ligand exchange, and electron transfer dynamics of small gold nanoparticles
 
I. Catalytic redox-initiated glycolate aldol additions of silyl glyoxylates. II. Diastereoselective de novo synthesis of pentasubstituted gamma-butyrolactones from silyl glyoxylates and ketones via double Reformatsky reactions. III. Progress toward the total synthesis of leustroducsin B
 I. Enantioselective metallophosphite-catalyzed aza-benzoin reaction between acyl silanes and nitrones. II. Lanthanum tricyanide-catalyzed acyl silane-ketone benzoin additions and kinetic resolution of resultant alpha-silyloxyketones. III. Bis-functionalization of glyoxylate for the synthesis of fully substituted glycolic acids
 
Total Synthesis of Spirofungins A and B and Formal Synthesis of the C1-C38 Fragment of (+)-Sorangicin A
 Complexity-building transformations of silyl glyoxylates
 
Synthetic studies on silyl glyoximines, alternaric acid, and quaternary donor site cyclopropanes
 Vinylogous Michael Cascade Reactions Employing Silyl Glyoxylates and Silyl Glyoximides
 
Rational design of high performance conjugated polymers for organic solar cells
 The Synthesis and Optimization of Conjugated Polymers for Photovoltaic Applications
 
Characterization and simulation of isoprene photooxidation from smog chamber studies
 Expanding the Scope of Thiophene Based Semiconductors: Perfluoroalkylated Materials and Fused Thienoacenes
 
Total synthesis of the proposed structure of aldingenin B
 Strategies for the synthesis and use of beta-stereogenic alpha-keto esters
 
Synthesis of hybrid inorganic/organic nitric oxide-releasing silica nanoparticles for biomedical applications