Studies of high pressure and high temperature physical properties of liquid FeS and gallium using synchrotron x-ray
by Yu, Tony, Ph.D., STATE UNIVERSITY OF NEW YORK AT STONY BROOK, 2009, 103 pages; 3393676

Abstract:

The interior of the earth has always been of great interest to geoscientists. Due to the inaccessibility of samples from deep earth, we have been relying upon other scientific methods and procedures to explore the earth’s interior. Cosmochemical and geochemical studies of samples from shallow earth suggest that the core is mainly consisted of Fe, Ni, and one or more lighter elements. Previous investigations from seismic data and mineral physics data indicate that the outer core’s density is about 6% to 10% less than that of pure Fe at the outer core’s pressure and temperature conditions, and thus there must be a significant amount of a light element or various kinds of light elements existing in the outer core. The light element candidates in the outer core include C, H, O, S, Si, and the caused density variation might play a critical role in the liquid outer core convection. Using the x-ray absorption radiograph system, we have successfully measured the density of liquid phase FeS at 1673K and up to 5.6GPa in pressure. Our self-developed absorption image fitting program has proved to be reliable in determining the density of liquid FeS. The 15.4 GPa isothermal bulk modulus of liquid FeS at 1673K derived from the density compression curve provides information in constraining the sulfur content in the liquid outer core, which is one of the strong light element candidates that might be responsible for the density deficit in the outer core. To further understand the liquid behavior under extreme condition, we used the pair distribution function (PDF) method to study the structure of an elemental liquid—gallium and its atomic structure change due to compression. Diffuse scattering data were collected over the whole pressure range of liquid state (0.1-2GPa) at ambient temperature. The PDF results show that the first nearest neighbor peak position did not change with pressure increasing, while the farther peaks positions in the intermediate distance range decreased with pressure increasing. This leads to a conclusion of the possible existence of “locally rigid units” in the liquid. With the addition of a series of reverse Monte Carlo modeling of the liquid structure, we have observed that the coordination number in the local rigid unit increases with pressure. The bulk modulus of liquid gallium derived from the volume compression curve at ambient temperature is 12.1(6) GPa.

 
AdviserJiuhua Chen
SchoolSTATE UNIVERSITY OF NEW YORK AT STONY BROOK
SourceDAI/B 71-02, p. , Mar 2010
Source TypeDissertation
SubjectsGeophysics
Publication Number3393676
Adobe PDF Access the complete dissertation:
 

» Find an electronic copy at your library.
  Use the link below to access a full citation record of this graduate work:
  http://gateway.proquest.com/openurl%3furl_ver=Z39.88-2004%26res_dat=xri:pqdiss%26rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation%26rft_dat=xri:pqdiss:3393676
  If your library subscribes to the ProQuest Dissertations & Theses (PQDT) database, you may be entitled to a free electronic version of this graduate work. If not, you will have the option to purchase one, and access a 24 page preview for free (if available).

About ProQuest Dissertations & Theses
With over 2.3 million records, the ProQuest Dissertations & Theses (PQDT) database is the most comprehensive collection of dissertations and theses in the world. It is the database of record for graduate research.

The database includes citations of graduate works ranging from the first U.S. dissertation, accepted in 1861, to those accepted as recently as last semester. Of the 2.3 million graduate works included in the database, ProQuest offers more than 1.9 million in full text formats. Of those, over 860,000 are available in PDF format. More than 60,000 dissertations and theses are added to the database each year.

If you have questions, please feel free to visit the ProQuest Web site - http://www.proquest.com - or call ProQuest Hotline Customer Support at 1-800-521-3042.