Transparent conductive carbon nanotubes coated flexible substrate and its application for electronic devices
by Rahy, Abdelaziz, Ph.D., THE UNIVERSITY OF TEXAS AT DALLAS, 2008, 93 pages; 3340492

Abstract:

The primary goal of this project was to develop a flexible transparent conductor with 100 Ω/sq with 90% transmittance in the wavelength range of 400-700nm on a flexible substrate. A second objective was to simplify the coating process to be commercially viable. The best result achieved so far was 110 Ω/sq at 88% transmittance using purified single walled nanotubes (SWNTs) coated on a polyethylene naphthalate (PEN) substrate on both sides. The SWNT sample used was purchased from Carbon Nanotechnologies Inc (CNI). Proper sonication of the single walled nanotubes (SWNTs) with a proper solvent selection with no use of surfactant simplified the overall coating procedure from five steps (prior art method) to three steps utilizing a dip coating method.

We also found that the use of metallic SWNTs can significantly improve the conductivity and transmittance compared with the use of mixed SWNTs, i.e., unseparated SWNTs We also studied a possible adhesion mechanism between SWNTs and the surface of PEN; we concluded that π - π stacking effect and hydrophobic-to-hydrophobic interaction are the major contributing factors to have CNTs adhere on the surface of the PEN substrate. Working devices of polymer light emitting diodes (PLEDs) and solar cell were successfully fabricated using SWNT coated substrates. A no optimized PLEDs device exhibited low turn-on voltage (∼5V), and the fabricated solar cell functioned. The devices have demonstrated the coated film can be used for potential electronic devices.

 
AdviserDuck Joo Yang
SchoolTHE UNIVERSITY OF TEXAS AT DALLAS
SourceDAI/B 69-12, p. , Mar 2009
Source TypeDissertation
SubjectsPolymer chemistry; Electrical engineering; Energy; Materials Science
Publication Number3340492
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