UMI  
ProQuest® Dissertations & Theses
The world's most comprehensive collection of dissertations and theses. Learn more...
ProQuest  
 
 
Jammed packings of hard particles
by Donev, Aleksandar, PhD, PRINCETON UNIVERSITY, 2006, 0 pages; 3214559
 

Abstract: This dissertation describes an investigation of jammed packings of frictionless hard particles, including the computer generation of (nearly) jammed packings, the development of mathematical criteria and algorithms to verify jamming, and computational and experimental studies of disordered and ordered hard-sphere and hard-ellipsoid packings. In the first part of this dissertation a mathematical framework for understanding jamming in packings of hard particles is developed. Algorithms to model hard-particle systems, and in particular, a collision-driven molecular dynamics algorithm for the simulation of dense packings of hard spheres, ellipsoids and superellipsoids, are designed. This algorithm is used to implement a generalization of the Lubachevsky-Stillinger algorithm to generate disordered packings of hard spheres and hard ellipsoids. It is found that the density and average contact number of the random packings rises sharply, but continuously, as asphericity is introduced, leading to hypostatic packings much denser than well-known random sphere packings. A mathematical theory of jamming for packings of spherical and nonspherical particles, as well as algorithms to test whether a packing is (nearly) jammed are developed, verifying that our packings are jammed. A molecular-dynamics algorithm to calculate the (non-equilibrium) free energy of nearly jammed packings of hard particles is designed and implemented. In the second part of this dissertation the properties of disordered and ordered packings of hard particles are studied. Investigated are correlations, including short-ranged order in the pair-correlation function, as well as long-ranged density fluctuations in the structure factor, for hard sphere packings in both three and higher dimensions. An unusual multitude of near contacts persistent with dimensionality, as well as a decorrelation for distances beyond contact as dimension increases, are found. Comparisons find good agreement between computational and experimental results for packing of hard ellipsoids in finite containers. The densest known ordered packing of hard ellipsoids is discovered using molecular dynamics. Finally, the thermodynamics of dense systems of hard-particles is investigated. The phase-diagram of hard rectangles of aspect ratio two (dominos) is determined. Finally, it is demonstrated that there is no ideal glass transition for binary systems of hard disks.

 
Advisor: Torquato, Salvatore
School: PRINCETON UNIVERSITY
Source: DAI-B 67/04, p. 2015, Oct 2006
Source Type: PhD
Subjects: Chemistry; Mathematics
Publication Number: 3214559
     
Adobe PDF Access the complete dissertation:
 

» Find an electronic copy at your library.
  Use the link below to access a full citation record of this graduate work:
  http://gateway.proquest.com/openurl%3furl_ver=Z39.88-2004%26res_dat=xri:pqdiss%26rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation%26rft_dat=xri:pqdiss:3214559
  If your library subscribes to the ProQuest Dissertations & Theses (PQDT) database, you may be entitled to a free electronic version of this graduate work. If not, you will have the option to purchase one, and access a 24 page preview for free (if available).

 
 
 

About ProQuest Dissertations & Theses
With over 2.3 million records, the ProQuest Dissertations & Theses (PQDT) database is the most comprehensive collection of dissertations and theses in the world. It is the database of record for graduate research.

The database includes citations of graduate works ranging from the first U.S. dissertation, accepted in 1861, to those accepted as recently as last semester. Of the 2.3 million graduate works included in the database, ProQuest offers more than 1.9 million in full text formats. Of those, over 860,000 are available in PDF format. More than 60,000 dissertations and theses are added to the database each year.

If you have questions, please feel free to visit the ProQuest Web site - http://www.il.proquest.com - or call ProQuest Hotline Customer Support at 1-800-521-3042.



Copyright © 2007 ProQuest. All rights reserved. Terms and Conditions

ProQuest