Biodegradable blends of poly (lactic acid) (PLA) / polyhydroxybutrate (PHB) copolymer and its effects on rheological, thermal and mechanical properties
by Sood, Nitin K., M.S., UNIVERSITY OF MASSACHUSETTS LOWELL, 2010, 64 pages; 1486818

Abstract:

Poly (Lactic acid) is the most important plastic derived from the renewable resources. PLA based products have extensively been used in the medical industry. However, PLA has a few disadvantages such as inherent brittleness and low toughness despite a high modulus.

A focus of this experiment was to study the improvement in toughness of PLA and to study the changes in thermal and rheological properties by blending PLA with a PHB copolymer. Where, PLA and PHB copolymer were melt blended using a twin screw Brabender extruder in the ratios of 100/0, 70/30, 50/50, 30/70, 0/100. Further, the blends were injection molded into tensile bar and impact bars for mechanical testing.

Rheological properties were studied using a Galaxy capillary rheometer for melt viscosities and temperature dependence indicated a shear-thinning behavior along with power law model and consistency index. Blends were characterized to study the phase model using a differential scanning calorimetric (DSC), showed two separate phases. Mechanical properties were analyzed using a Tensile and Izod impact test indicating decrease in elastic modulus with increase in toughness and elongation as the PHB copolymer content was increased in the blend.

 
AdviserStephen P. McCarthy
SchoolUNIVERSITY OF MASSACHUSETTS LOWELL
SourceMAI/ 49-02, p. , Oct 2010
Source TypeThesis
SubjectsBiomedical engineering; Materials Science; Plastics
Publication Number1486818
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